Congrats on your 100W (I only have a 20W so my options are fewer than yours).
I suppose I should ask, what is your design intent?
Some materials can have a number of procedures performed unto them, while others cannot.
Do you want to:
-Engrave (removes some of the surface)
-Anneal (changes the structure of the surface or oxidizes it at times, creating a different shade without removing material)
-Foam (material heats and bubbles outwards, creating a raised surface)
-Frost (some materials get a change in their surface that resembles a soft-sanded look)
-Cut (cut through a material's thickness entirely)
Perhaps you should provide the materials you're intending to work on?
I can probably tell you some settings, though as I said, my machine is lighter on the watts in comparison to yours.