Hi.....200 X 200 X10.....wow, that is going to be a very big biggie.
The problem is, with tubing that size, and I assume the overall frame size/length will be out of this World....you won't be able to successfully align the two rails for the Y axis with any degree of accuracy, and straight edges that span that distance would cost more than the machine itself, so to answer your question, I think self leveling epoxy with a retaining wall around the edges of the rail mount to contain the epoxy could do the trick.
You don't want to make it too thick as this will make it compressible and unstable.......how thick?......God knows.
There's no other real way to get a long structure truly flat and level, and we're talking about tenths of a mil over 10 metres or so.....the moment you move it, it will bend and/or twist to some degree, so the build would work best if it was assembled in the position it is going to work on.
Initial leveling with a good bubble level will help, and spot checking along the length with a straight edge too.
Ian.