Most likely if you buy a UC100 off Ebay it is likely to be a fake, and is not supported with the software for the real UC100, so don't buy one from Ebay
Windows7 32 Bit with a Parallel Port do work with Mach 3
Have you checked that the parallel port is working, go to Control Panel Device Manager. Is the new parallel port listed? hook up an old printer to see if you can get it to print, if that part is working then Mach3 will work, don't watch to many videos unless they are from the Mach web site Newfangled Solutions » CNC Software Home of Mach3 what works for them, may not work for you, not all setups are the same